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ChemInform Abstract: Reductive Cyanation: A Key Step for a Short Synthesis of (-)-(2S,3S)-3-Hydroxyproline.

✍ Scribed by J.-O. DURAND; M. LARCHEVEQUE; Y. PETIT

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Reductive Cyanation: A Key Step for a Short Synthesis of (-)-(2S,3S)-3-Hydroxyproline.

-A short, stereoselective synthesis of a 3-hydroxyproline (VII) starting from L-malic acid is described. Key step is a stereospecific reductive cyanation of compound (IV), which leads in contrast to former studies to the trans-isomer. -(DURAND,

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