ChemInform Abstract: Reductive Chloro- and Thioallylations: Stereoselective Two-Step Transformations of Esters and Lactones into Functionalized cis- and trans-Vinyloxiranes.

Reductive Chloro- and Thioallylations: S

Reductive Chloro- and Thioallylations: Stereoselective Two-Step Transformations of Esters and Lactones into Functionalized cis- and trans-Vinyloxiranes

✍ Christian Hertweck; Wilhelm Boland 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 255 KB

A practical and straightforward procedure is described for diastereoselectivities. The β-hydroxy intermediates were stereoselectively converted into the corresponding cis-or the diastereoselective synthesis of functionalized cis-and trans-vinyloxiranes. Readily available esters and lactones trans-vi