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ChemInform Abstract: Reassignment of the Configuration of Several Ketocyclolignans Prepared from Podophyllotoxin.

✍ Scribed by J. M. MIGUEL DEL CORRAL; M. GORDALIZA; J.-L. LOPEZ; E. DEL OLMO; M. A. CASTRO; M. L. LOPEZ

Book ID
112027413
Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
27
Category
Article
ISSN
0931-7597

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Reassignment of the Configuration of Sev
Reassignment of the Configuration of Several Keto-cyclolignans Prepared from Podophyllotoxin
✍ JosΓ© MarΓ­a Miguel del Corral; Marina Gordaliza; JosΓ©-Luis LΓ³pez; Esther Del Olmo πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 German βš– 185 KB

The configuration of several keto-cyclolignans reiated to podophyllotoxin has been reviewed. Under basic catalysis, the configuration at the C-atom in a -position to the lactone carbonyl group in podophyllotoxone is inverted instead of the C-atom in a-position to the ketone group, as it has been rep