ChemInform Abstract: Rearrangement of Lithioalkynyltriorganoborates Derived from Propargylic Acetals: A One-Pot Synthesis of Homopropargylic Alcohols.
β Scribed by D. CARRIE; B. CARBONI; M. VAULTIER
- Book ID
- 112027870
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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Efficient One-Pot Synthesis of Propargylstannanes from Propargylic Alcohol Derivatives via Allenyltitaniums. -The reaction of propargylic carbonates (I) with a Ti(OiPr) 4 /iPr-MgCl reagent combination followed by treatment with Bu 3 SnCl affords mixtures of propargylstannanes (III) and allenylstann
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