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ChemInform Abstract: Rearrangement Approaches to Cyclic Skeletons. Part 10. Pinacol-Type Rearrangement of 2-Substituted 1-Methoxybicyclo(2.2.2)oct-5-en-2-ols into Bicyclo(3.2.1)oct-6-en-2-ones. Remarkable Substituent Effects on Predominant Migration of the Unsaturated Bridge.

โœ Scribed by T. UYEHARA; T. INAYAMA; T. FURUTA; T. KATO; Y. YAMAMOTO; M. UENO; T. SATO


Book ID
112039135
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
27
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Stereoconvergent Ap
โœ Hiroki Hashimoto; Katsura Seki; Masako Ueno; Toshio Sato; Tadao Uyehara ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 34 KB ๐Ÿ‘ 2 views

Stereoconvergent Approach to Each of the Stereoisomeric Hydroxydiquinanes Based on the Anionic [1,3] Rearrangement of Bicyclo[3.2.1]oct-6-en-2-ols. -The anionic [1,3] rearrangement of both stereoisomeric bicyclo-octenols (I) and (IV) by treatment with KN(Tms) 2 in toluene or diglyme takes place as