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ChemInform Abstract: Reactivity of the Si-C Bond of (1)Silaferrocenophane: Palladium- Catalyzed Dimerization and Oxidative Addition to a Pt(0) Complex.

✍ Scribed by N. P. REDDY; N. CHOI; S. SHIMADA; M. TANAKA


Book ID
112042106
Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
27
Category
Article
ISSN
0931-7597

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## Abstract The chemical reduction of Pt(acac)~2~ by DIBALH in the presence of phosphanes, which is used to generate active Pt^0^ complexes in the Pt‐catalyzed silaboration of cyclohexadiene by 2‐(dimethylphenylsilyl)‐4,4,5,5‐tetramethyl‐1,3,2‐dioxaborolane (1) leading to the 1,4‐silaborated produc