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ChemInform Abstract: Reactivity of the 5-Hydroacenaphthylene Anion Towards Electrophiles.

โœ Scribed by M. E. VAN LOO; J. LUGTENBURG; J. CORNELISSE


Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
29
Category
Article
ISSN
0931-7597

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Reactivity of the 5-Hydroacenaphthylene
โœ Marcia E. Van Loo; Johan Lugtenburg; Jan Cornelisse ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 382 KB ๐Ÿ‘ 1 views

The dianion of acenaphthylene can be converted into the 5-unsaturated bromides is responsible for this side reaction. From the products of the reactions with 3,3-dimethylallyl hydroanion by protonation with one equivalent of methanol. Subsequent reaction with electrophiles such as allyl bromide bro