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ChemInform Abstract: Reactivity of Chelating Dicarbene Metal Complex Catalysts. Part 2. Highly Efficient Alkyne Hydroarylation with Chelating Dicarbene Palladium(II) and Platinum(II) Complexes.

✍ Scribed by Andrea Biffis; Cristina Tubaro; Gabriella Buscemi; Marino Basato


Publisher
John Wiley and Sons
Year
2008
Weight
37 KB
Volume
39
Category
Article
ISSN
0931-7597

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Highly Efficient Alkyne Hydroarylation w
✍ Andrea Biffis; Cristina Tubaro; Gabriella Buscemi; Marino Basato 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 210 KB 👁 2 views

## Abstract 1 We report on a novel reaction protocol for the coupling of arenes with alkynes (the Fujiwara reaction), yielding products of formal __trans__‐hydroarylation of the triple bond. The protocol makes use of a chelating N‐heterocyclic dicarbene palladium(II) complex as catalyst and allows