Reactivity Control in the Addition of N,
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Sara López-Tosco; David Tejedor; Javier González-Platas; Fernando García-Tellado
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Article
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2011
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John Wiley and Sons
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English
⚖ 322 KB
## Abstract A metal‐free domino reaction for the synthesis of a new family of fused bicyclic 1,4‐diazepanes and 1,5‐diazocanes has been developed. The reaction involves the use of __N__,__N′__‐dialkylated 1,__n__‐diamines as the nitrogen source, through‐space orbital interactions between the two ni