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ChemInform Abstract: Reactivity Control in the Addition of N,N′-Dialkylated 1,n-Diamines to Activated Skipped Diynes: Synthesis of Fused Bicyclic 1,4-Diazepanes and 1,5-Diazocanes.

✍ Scribed by Sara Lopez-Tosco; David Tejedor; Javier Gonzalez-Platas; Fernando Garcia-Tellado


Book ID
112044039
Publisher
John Wiley and Sons
Year
2012
Weight
33 KB
Volume
43
Category
Article
ISSN
0931-7597

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Reactivity Control in the Addition of N,
✍ Sara López-Tosco; David Tejedor; Javier González-Platas; Fernando García-Tellado 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 322 KB

## Abstract A metal‐free domino reaction for the synthesis of a new family of fused bicyclic 1,4‐diazepanes and 1,5‐diazocanes has been developed. The reaction involves the use of __N__,__N′__‐dialkylated 1,__n__‐diamines as the nitrogen source, through‐space orbital interactions between the two ni