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ChemInform Abstract: Reactions of Tin(IV) Enolates and Radicals Derived from the Tin Hydride Scission of Cyclopropyl Ketones.

โœ Scribed by E. J. ENHOLM; Z. J. JIA

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
28
Category
Article
ISSN
0931-7597

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The Chemistry and Reactivity of Aryl Radicals -The C-C Bond Formation from o-Bromobenzylphenylethers with Tin Hydride and Azobisisobutyronitrile. -In the presence of Bu3SnH and 0.5-0.6 equiv. of AIBN o-bromobenzylphenyl ethers are found to undergo 1,6-and/or 1,5-ring closure yielding benzopyrans an