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ChemInform Abstract: Reactions of Methacryloyl Isocyanate with Imines Derived from Ketones and Alkyl Amines.

✍ Scribed by O. TSUGE; T. HATTA; M. KUWATA; T. YAMASHITA; A. KAKEHI

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Reactions of Methacryloyl Isocyanate with Imines Derived from Ketones and Alkyl Amines.

-Methacryloyl isocyanate (I) reacts with imines such as (II) and (V) to form ureas (III) and/or oxazine derivatives (IV) and (VI) depending on the reaction conditions as well as the nature of the imine. The formation of these products presumably proceeds via intermediate enamine tautomers of imines.

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