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ChemInform Abstract: Reactions of Cyclic Diynes with Acceptor-Substituted Alkynes: Syntheses of Doubly Bridged Dewar Benzenes.

✍ Scribed by R. GLEITER; F. OHLBACH; T. OESER; H. IRNGARTINGER


Book ID
112037625
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
27
Category
Article
ISSN
0931-7597

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Reactions of Cyclic Diynes with Acceptor
✍ Gleiter, Rolf ;Ohlbach, Frank ;Oeser, Thomas ;Irngartinger, Hermann 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 672 KB

## Abstract The reaction of the AlCl~3~ complex of cyclic diynes (mainly a 14‐membered ring) with dimethyl acetylenedicarboxylate (DMAD) or bis(__tert__‐butylsulfonyl)acetylene (BTSA) and related compounds was investigated. The reaction of the AlCl~3~ complex of cyclotetradeca‐1,8‐diyne (1, __n__ =