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ChemInform Abstract: Reactions of Carbanions with 1,3-Benzodioxin-4-ones: Facile Routes to Flavones, Aurones, and Acyl Phloroglucinols.

✍ Scribed by George A. Kraus; Jingqiang Wie; Aniket Thite


Publisher
John Wiley and Sons
Year
2008
Weight
45 KB
Volume
39
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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Reaction of 2,2,6-Trimethyl-4H-1,3-dioxin-4-one with Imines: An Easy Route to Enamides. -Thermolysis of the dioxin (I) generates an acylketene which is readily trapped by imines to give the N-alkenyl acetoacetamides (III). They are useful intermediates in oxidative radical cyclizations leading to .