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ChemInform Abstract: Reactions of 6-Aminopyrimidin-4(3H)-ones with Electron-Deficient Alkenyl Derivatives. Easy Preparation of Heterocyclic Analogues of Sangivamicine.

✍ Scribed by J. COBO; A. SANCHEZ; M. NOGUERAS

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Reactions of 6-Aminopyrimidin-4(3H)-ones with Electron-Deficient Alkenyl Derivatives. Easy Preparation of Heterocyclic Analogues of Sangivamicine.

-6-Aminopyrimidines like (I) and (VII) are found to react with maleimide to afford Michael adducts. In one case small amounts of a pyrrolopyridine, arising from Diels-Alder reaction, are also isolated. The reaction with more reactive maleic anhydride leads to pyrrolopyrimidines (analogues of sangivamicine) formed by cyclization of the Michael adducts.

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