ChemInform Abstract: Reactions Involving Fluoride Ion. Part 41. Synthesis of Hexakis( trifluoromethyl)cyclopentadiene and Derived Cyclopentadienide Salts.

✍ Scribed by R. D. CHAMBERS; W. K. GRAY; J. F. S. VAUGHAN; S. R. KORN; M. MEDEBIELLE; A. S. BATSANOV; C. W. LEHMANN; J. A. K. HOWARD

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 31 KB
• Volume: 28
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199722075

✦ Synopsis

Reactions Involving Fluoride Ion. Part 41. Synthesis of Hexakis( trifluoromethyl)cyclopentadiene and Derived Cyclopentadienide Salts.

-The title compound (III) is synthesized with a view to the attachment of fluorinated cyclopentadienide ligands to transition metals. Various donors promote one-electron transfer to (III) leading to the corresponding cyclopentadienide salts, e.g. (V) and (VII). -(CHAMBERS, R. D.; GRAY,