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ChemInform Abstract: Reaction with Hydrazonoyl Halides. Part 23. Synthesis and Reactions of C-Coumarinoyl-N-arylformohydrazonoyl Bromides.

โœ Scribed by Abdou O. Abdelhamid; Gaber S. Mohamed


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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Reaction with hydrazonoyl halides XXIII
โœ Abdou O. Abdelhamid; Gaber S. Mohamed ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 195 KB ๐Ÿ‘ 2 views

C-Coumarinoyl-N-arylformohydrazonoyl bromides (3) were synthesized by reaction of Nnitrosoarylacetamides with an appropriate sulfonium bromide in ethanol at room temperature. The reactions of potassium thiocyanate, potassium selenocyanate, thiourea, methyl phenylthiocarbomate, and methyl phenylhydra

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## Abstract Cโ€acylโ€Nโ€(3โ€phenylโ€5โ€pyrazolyl)hydrazonoyl chlorides **1a,b** react with potassium thiocyanate and potassium selenocyanate to give 5โ€acylโ€2,3โ€dihydroโ€2โ€iminoโ€3โ€(3โ€ฒโ€phenyl)pyrazolโ€5โ€ฒโ€yl)โ€1,3,4โ€thiadiazoles **2a,b** and 5โ€acetylโ€2,3โ€dihydro;โ€2โ€iminoโ€3โ€(3โ€ฒโ€phenyl)pyrazolโ€5โ€ฒโ€yl)โ€1,3,4โ€selen