C-Coumarinoyl-N-arylformohydrazonoyl bromides (3) were synthesized by reaction of Nnitrosoarylacetamides with an appropriate sulfonium bromide in ethanol at room temperature. The reactions of potassium thiocyanate, potassium selenocyanate, thiourea, methyl phenylthiocarbomate, and methyl phenylhydra
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ChemInform Abstract: Reaction with Hydrazonoyl Halides. Part 23. Synthesis and Reactions of C-Coumarinoyl-N-arylformohydrazonoyl Bromides.
โ Scribed by Abdou O. Abdelhamid; Gaber S. Mohamed
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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## Abstract CโacylโNโ(3โphenylโ5โpyrazolyl)hydrazonoyl chlorides **1a,b** react with potassium thiocyanate and potassium selenocyanate to give 5โacylโ2,3โdihydroโ2โiminoโ3โ(3โฒโphenyl)pyrazolโ5โฒโyl)โ1,3,4โthiadiazoles **2a,b** and 5โacetylโ2,3โdihydro;โ2โiminoโ3โ(3โฒโphenyl)pyrazolโ5โฒโyl)โ1,3,4โselen