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ChemInform Abstract: Reaction of Vinylpyridines with Active Modifications of Elemental Phosphorus in KOH/DMSO.

โœ Scribed by N. K. Gusarova; S. I. Shaikhudinova; T. I. Kazantseva; B. G. Sukhov; V. I. Dmitriev; L. M. Sinegovskaya; Yu. V. Smetannikov; N. P. Tarasova; B. A. Trofimov


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
33
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Electrophilic React
โœ M. A. KAZANKOVA; I. G. TROSTYANSKAYA; I. V. EFIMOVA; I. P. BELETSKAYA ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 32 KB ๐Ÿ‘ 1 views

The base mediated reactions of alkenyl alkyl ethers (cf. (I), (III), ( V)) as well as ketene acetals (VII) with phosphorus trihalides result in the unprecedented electrophilic substitution of a vinylic hydrogen by a dihalogenophosphine group furnishing (alkoxyalkenyl) dihalogenophosphines in good yi