ChemInform Abstract: Reaction of Silyl(carbonyl)iron Complexes with LiAlH4 Giving Methylsilanes: Reduction of a Carbonyl Ligand and Coupling with a Silyl Group.

✍ Scribed by H. TOBITA; R. SHIOZAWA; H. OGINO

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 29 KB
• Volume: 28
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199749186

✦ Synopsis

1997 organo-silicon compounds, isocyclic C derivatives organo-silicon compounds, isocyclic C derivatives S 0064

49 -186

Reaction of Silyl(carbonyl)iron Complexes with LiAlH4 Giving Methylsilanes: Reduction of a Carbonyl Ligand and Coupling with a Silyl Group.

-Labeling experiments using LiAlD4 prove unambiguously that the carbonyl ligand is reduced with LiAlH4 and coupled with the silyl group to give the methylsilane (II). -(TOBITA, H.;