ChemInform Abstract: Reaction of Pyrylium Salts with Nucleophiles. Part 25. Formation of Pyridine-1-oxides, 2-Isoxazolines and 1-Pyrazoline-1-oxides.
β Scribed by C. UNCUTA; M. R. CAPROIU; V. CAMPEANU; A. PETRIDE; M. G. DANILA; M. PLAVETI; A. T. BALABAN
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 37 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Reaction of Pyrylium Salts with Nucleophiles. Part 25. Formation of Pyridine-1-oxides, 2-Isoxazolines and 1-Pyrazoline-1-oxides.
-The competitive formation of pyridine-1-oxides and 2-isoxazolines from reaction of pyrylium salts with hydroxylamine is investigated. The synthetic value of pyrylium salts for the preparation of 2-isoxazolines is emphasized for the first time.
π SIMILAR VOLUMES
Chemistry of Pyridine N-Oxides. Part 5. Cine Substitution in Reaction of Unactivated 2-Halopyridines with 2-Aminopyridine 1-Oxide. Formation of 3-(2-Pyridylamino)-2(1H)-pyridone. -Treatment of oxide (I) with 2-bromopyridine (II) results surprisingly in the formation of the cine substitution product
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