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ChemInform Abstract: Reaction of Maleimides with New Silyloxydienes, 2-Amino-4-(trimethylsilyloxy)-1,3-pentadienes.

✍ Scribed by O. TSUGE; T. HATTA; Y. TAKAHASHI; H. MAEDA; A. KAKEHI

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Reaction of Maleimides with New Silyloxydienes, 2-Amino-4-(trimethylsilyloxy)-1,3-pentadienes.

-Enolization of enaminones such as (I) gives new siloxydienes which react with maleimides to yield besides the Diels-Alder adducts a number of side products depending on the reaction conditions. Interestingly, the dienic product (VI) adds to dimethyl acetylenedicarboxylate (IX) to provide the cyclooctatriene (X). -(TSUGE, O.; HATTA,

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