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ChemInform Abstract: Reaction of Hydroxycarboxylic Acid Amides and Their O-Trimethylsilyl Derivatives with Dimethyl(chloromethyl)chlorosilane. Synthesis of 6- Membered 1-Oxa-4-aza-2-sila- and 1-Oxa-4-aza-2,6-disilacyclanes.

✍ Scribed by YU. I. BAUKOV; A. G. SHIPOV; E. P. KRAMAROVA; E. A. MAMAEVA; O. A. ZAMYSHLYAEVA; N. A. ANISIMOVA; V. V. NEGREBETSKII

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199721177

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✦ Synopsis

Reaction of Hydroxycarboxylic Acid Amides and Their O-Trimethylsilyl Derivatives with Dimethyl(chloromethyl)chlorosilane. Synthesis of 6-Membered 1-Oxa-4-aza-2-sila-and 1-Oxa-4-aza-2,6-disilacyclanes.

-New and general methods for the synthesis of the title Si-heterocycles (cf. (IV) and (VI), resp.) based on the reaction of chloromethylsilane (II) with hydroxycarboxylic amide derivatives or simple carboxylic amides, resp., are given.

-(BAUKOV, YU. I.; SHIPOV, A.

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