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ChemInform Abstract: Reaction of Hydrosilanes with Carbon Dioxide, Secondary Amines or Silylamines.

✍ Scribed by A. D. KIRILIN; A. A. DOKUCHAEV; I. N. MENCHAIKINA; E. V. SEMENOVA; N. B. SOKOVA; E. A. CHERNYSHEV

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Reaction of Hydrosilanes with Carbon Dioxide, Secondary Amines or Silylamines.

-The reaction of hydrosilanes with carbon dioxide and amines is studied for the first time. Composition and structure of the obtained products depend on the nature of reagents used and the reaction conditions. The previously unknown hydrosilane-CO2 system is shown to be a useful reagent for N-siloxycarbonylation (β†’ (IV), (XI)). -(KIRILIN, A. D.; DOKUCHAEV, A.

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