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ChemInform Abstract: Reaction of Herz Salts with Malononitrile: A General Route to (6H-1,2,3-Benzodithiazol-6-ylidene)malononitriles.

✍ Scribed by Panayiotis A. Koutentis; Charles W. Rees


Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
33
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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ChemInform Abstract: Reaction of 2,2,6-T
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Reaction of 2,2,6-Trimethyl-4H-1,3-dioxin-4-one with Imines: An Easy Route to Enamides. -Thermolysis of the dioxin (I) generates an acylketene which is readily trapped by imines to give the N-alkenyl acetoacetamides (III). They are useful intermediates in oxidative radical cyclizations leading to .