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ChemInform Abstract: Reaction of Ethyl Chlorocyanonitroacetate with 3-Chlorobenzonitrile Oxide.

โœ Scribed by A. G. Tyrkov; I. V. Krivova

Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
30
Category
Article
ISSN
0931-7597

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โœ M. KAEGI; G. MLOSTON; H. HEIMGARTNER ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 36 KB ๐Ÿ‘ 1 views

Reactions of Ethyl Diazoacetate with Thioketones. -The 1,3-dipolar cycloaddition of ethyl diazoacetate (II) with thioketones is investigated. The most reactive dipolarophiles (I) give 1,3-dithiolanes, e.g. (III), (V), (VI) and (VIII). Sterically crowded thioketones (IX) and (XII) as well as the less