The Baylis-Hillman adducts of aryl aldehydes and alkyl acrylates are efficiently oxidized to the corresponding a-methylene-b-keto esters with the Dess-Martin periodinane. The attempted Swern oxidation of the same adducts resulted in S N 2%-type substitution of the allylic hydroxyl group by chloride.
ChemInform Abstract: Reaction of Baylis—Hillman Products with Swern and Dess—Martin Oxidants.
✍ Scribed by Nicholas J. Lawrence; J. Paul Crump; Alan T. McGown; John A. Hadfield
- Book ID
- 101912261
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v