ChemInform Abstract: Reaction of 5-Methyl-2-piperidino-1,3-dithiolium 4-Thiolate. Novel Substituted Tetrathiafulvalenes and Tetracyanoquinodimethane Salts with Cations Containing Long Aliphatic Radicals for Langmuir—Blodgett Technology.
✍ Scribed by G. G. ABASHEV; E. V. SHKLYAEVA; V. S. RUSSKIKH
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 35 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Reaction of 5-Methyl-2-piperidino-1,3-dithiolium 4-Thiolate. Novel Substituted Tetrathiafulvalenes and Tetracyanoquinodimethane Salts with Cations Containing Long Aliphatic Radicals for Langmuir-Blodgett Technology.
-Alkylation of the mesoionic salt (I) affords the new alkylthiodithiolium halides (III) which can be easily transformed into novel symmetric tetrathiafulvalenes (VI) and (VII) as well as novel unsymmetric tetrathiafulvalene (IX). Dithiolium salts bearing long aliphatic chains at the thiol sulfur such as (IIIe) provide easy access to Langmuir-Blodgett films on reaction with tetracyanoquinodimethane. -(ABASHEV, G. G.; SHKLYAEVA, E. V.;