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ChemInform Abstract: Rare Earth Metal Rich Magnesium Compounds Ln4NiMg (Ln: Y, Pr—Nd, Sm, Gd—Tm, Lu) — Synthesis, Structure, and Hydrogenation Behavior.

✍ Scribed by Selcan Tuncel; Jean Gabriel Roquefere; Cristina Stan; Jean-Louis Bobet; Bernard Chevalier; Etienne Gaudin; Rolf-Dieter Hoffmann; Ute Ch. Rodewald; Rainer Poettgen

Publisher
John Wiley and Sons
Year
2009
Weight
19 KB
Volume
40
Category
Article
ISSN
0931-7597

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The novel title compounds are prepared in about 90% yield by hydrothermal reaction of Ln2O3 with stoichiometric amounts of H3BO3 (H2O, 220 °C, autoclave, 3 d). The structures are investigated by powder XRD and single crystal XRD for Nd2B6O10(OH)4•H2O. The isostructural compounds crystallize in the m