ChemInform Abstract: Rare-Earth Germanium Antimonides Ln6Ge5-xSb11+x (Ln: La—Nd, Sm, Gd—Dy). Part 1. Syntheses and Structures.
✍ Scribed by Robert Lam; Robert McDonald; Arthur Mar
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 34 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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The novel title compounds are prepared in about 90% yield by hydrothermal reaction of Ln2O3 with stoichiometric amounts of H3BO3 (H2O, 220 °C, autoclave, 3 d). The structures are investigated by powder XRD and single crystal XRD for Nd2B6O10(OH)4•H2O. The isostructural compounds crystallize in the m