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ChemInform Abstract: Rapid Screening for Asymmetric Catalysts: The Efficient Connection of Two Different Catalytic Asymmetric Reactions.

✍ Scribed by Kazuhiro Yoshida; Takeharu Toyoshima; Naohisa Akashi; Tsuneo Imamoto; Akira Yanagisawa


Publisher
John Wiley and Sons
Year
2009
Weight
28 KB
Volume
40
Category
Article
ISSN
0931-7597

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Catalytic Asymmetric Diels-Alder Reactions of Ξ±-Thioacrylates for the Preparation of Norbornenone. -Cu(II)-catalyzed asymmetric Diels-Alder cycloaddition of Ξ±-thioacrylates (I) with excess cyclopentadiene using a bisoxazoline as chiral auxiliary provides the corresponding cycloadducts (III) in high