ChemInform Abstract: Rapid Access to Reactive Methanimines by the Retro-Ene Reaction: The Photoelectron Spectrum of N-Dimethylsilylmethanimine.

✍ Scribed by A. SYSTERMANS; V. LEFEVRE; J.-L. RIPOLL; T. PIEPLU; P. E. HOGGAN; S. JOANTEGUY; A. CHROSTOWSKA-SENIO; G. PFISTER-GUILLOUZO

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 28 KB
• Volume: 28
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199737070

✦ Synopsis

Rapid Access to Reactive Methanimines by the Retro-Ene Reaction:

The Photoelectron Spectrum of N-Dimethylsilylmethanimine.

-An improved synthesis of the parent compound (II), trapped as thioether (IV), and similarly of silyl derivative (VII) is achieved by flash vacuum thermolysis of amines (I) or (V). -(SYSTERMANS, A.;