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ChemInform Abstract: Radical Rearrangements of α-Iodoalkyl Phenyl Sulfones Involving 1,5 Hydrogen Atom Transfer Reactions.

✍ Scribed by M. MASNYK

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199723102

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✦ Synopsis

1997 sulfoxides, sulfones, sulfenes and derivatives sulfoxides, sulfones, sulfenes and derivatives (benzene compounds) Q 0600

23 -102

Radical Rearrangements of α-Iodoalkyl Phenyl Sulfones Involving 1,5 Hydrogen Atom Transfer Reactions.

-Starting from iodinated sulfones such as (I), which can be prepared by a phase-transfer catalytic alkylation of iodomethyl phenyl sulfones, the title radical reaction leads to interesting intermediates for the synthesis of cyclopentanes. -(MASNYK,

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