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ChemInform Abstract: Radical Reactions in a Single Crystal of Phosphaalkene: EPR and ab initio Calculations of Phosphoniumyl Radical Cations.

✍ Scribed by S. N. BHAT; T. BERCLAZ; M. GEOFFROY; A. JOUAITI


Book ID
112028534
Publisher
John Wiley and Sons
Year
2010
Weight
24 KB
Volume
27
Category
Article
ISSN
0931-7597

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The geometry of the tive-membered ring (1) containing a phosphinyl radical is studied by ab initio molecular orbital calculations. X-irradiation of a single crystal of 1,3benzazaphosphole (2) generates the cyclic phosphinyl radical (3) whose EPR parameters are obtained and compared with those calcul