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ChemInform Abstract: Radical Carbonylations with Fluorous Allyltin Reagents.

✍ Scribed by Ilhyong Ryu; Tatsuro Niguma; Satoshi Minakata; Mitsuo Komatsu; Zhiyong Luo; Dennis P. Curran

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Radical Carbonylations with Fluorous Allyltin Reagents.

-A four-component reaction of organic halides, carbon monoxide, activated olefins, and propylene-spaced fluorous allyltin reagents is reported. The reaction successfully leads to Ξ²-functionalized Ξ²-allylated ketones. A biphasic work-up (MeCN/FC-72) is carried out to separate the products from the tin compounds.

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