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ChemInform Abstract: Radical Addition of Polyhaloalkanes to 2-Ethynyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane.

โœ Scribed by Tatsuya Wada; Yuto Sumida; Azusa Kondoh; Hideki Yorimitsu; Koichiro Oshima


Publisher
John Wiley and Sons
Year
2010
Weight
40 KB
Volume
41
Category
Article
ISSN
0931-7597

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study ( < -30"C)1111. This is best evidenced by the upfield shift of protons H' (by 23Hz) and H5 (by 32Hz) on going from ( 3 ) to ( 5 ) , which simply reflects the increased availability of the lone pair for limited delocalization but is clearly inconsistent with the development of the diamagnetic r