ChemInform Abstract: (R)-3,5-diCF3-SYNPHOS and (R)-p-CF3-SYNPHOS, Electron-Poor Diphosphines for Efficient Room Temperature Rh-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids.

✍ Scribed by Farouk Berhal; Olivier Esseiva; Charles-Henri Martin; Hitoshi Tone; Jean-Pierre Genet; Tahar Ayad; Virginie Ratovelomanana-Vidal

• Publisher: John Wiley and Sons
• Year: 2011
• Weight: 65 KB
• Volume: 42
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.201138029

✦ Synopsis

Abstract

Generally, higher yields and /or enantioselectivities are obtained with derivative (Ia).