Peptide Coupling Reactions with Phosphono-Phosphino Substituted γ-Thiapyrones -First Step to Unusual Peptides. -Chiral peptidosubstituted phosphono-phosphino γ-thiapyrones (III) are easily obtained by coupling of γ-thiapyrones (II) with protected amino acids (I) using perfluorophenyldiphenylphosphi
✦ LIBER ✦
ChemInform Abstract: Pyrylium Salts of γ-Thiapyrones — A Simple Step to Phosphono-phosphino Substituted Pyridines and Pyridinium Salts.
✍ Scribed by R. NEIDLEIN; D. U. HAHN
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Pyrylium Salts of γ-Thiapyrones -A Simple Step to Phosphonophosphino Substituted Pyridines and Pyridinium Salts.
-The recently reported pyrones (I) are easily converted to pyrylium salts (III). These [cf. (IIIa)] are converted to pyridines or pyridinium salts with ammonia or primary amines.
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