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ChemInform Abstract: Pyrimidine Anellated Heterocycles — Synthesis and Cycloaddition of the First Pyrimido[1,4]diazepine N-Oxides.

✍ Scribed by Frances Heaney; Cathriona Burke; Desmond Cunningham; Patrick McArdle

Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
32
Category
Article
ISSN
0931-7597

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Abstract

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ChemInform Abstract: Studies on Pyrimidine-Anellated Heterocycles: Synthesis of Pyrrolo[3,2-d]pyrimidines by Amine Oxide Rearrangement.
✍ K. C. MAJUMDAR; U. DAS; N. K. JANA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB

## Studies on Pyrimidine-Anellated Heterocycles: Synthesis of Pyrrolo [3,2-d]pyrimidines by Amine Oxide Rearrangement. -A number of pyrrolo[3,2-d]pyrimidine derivatives (VII) is synthesized in 90-95% yields from the corresponding uracils in a one-step process by treatment with MCPBA (VI). The C-C