ChemInform Abstract: Pseudocoenzyme B12 and Adenosyl-Factor A: Electrochemical Synthesis and Spectroscopic Analysis of Two Natural B12 Coenzymes with Predominantly “Base-off” Constitution.

Pseudocoenzyme B12 and Adenosyl-Factor A

Pseudocoenzyme B12 and Adenosyl-Factor A: Electrochemical Synthesis and Spectroscopic Analysis of Two Natural B12 Coenzymes with Predominantly ‘Base-off' Constitution

✍ Wolfgang Fieber; Bernd Hoffmann; Wolfgang Schmidt; Erhard Stupperich; Robert Kon 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 318 KB 👁 1 views

Pseudocoenzyme B 12 ( Cob-(5'-deoxy-5'-adenosyl)-(adenin-7-yl)cobamide; 1) and adenosyl-factor A ( Cob-(5'-deoxy-5'-adenosyl)-(2-methyladenin-7-yl)cobamide; 3) are two natural analogues of coenzyme B 12 ( adenosylcobalamin-Cob-(5'-deoxy-5'-adenosyl)-(5,6-dimethyl-1H-benzimidazolyl)cobamide; 2), wher