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ChemInform Abstract: Proof of Existence and Thermochemical Characterization of the Gaseous Molecule VOCl2.

✍ Scribed by A. HACKERT; V. PLIES; R. GRUEHN

Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Proof of Existence and Thermochemical Characterization of the Gaseous Molecule VOCl2.

-The existence of VOCl2 is proven by means of Knudsen-cell mass spectrometry. VOCl2 can be detected as a neutral gas phase product of the reaction between V2O3 and Cl2. The enthalpy of formation of gaseous VOCl2 is calculated to be βˆ†fH β€’ = -130.4 kcal/mol. -(HACKERT, A.;

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