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ChemInform Abstract: Preparation of α,β-Unsaturated Ketones Bearing a Trifluoromethyl Group and Their Application in Organic Synthesis

✍ Scribed by V. G. NENAJDENKO; A. V. SANIN; E. S. BALENKOVA


Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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✍ V. G. NENAJDENKO; A. L. KRASOVSKY; M. V. LEBEDEV; E. S. BALENKOVA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 38 KB

A Novel Efficient Synthesis of Heteroaryl Substituted α,β-Unsaturated Trifluoromethyl Ketones. -The novel electrophilic reagent (IV), easily prepared by reaction of phenyl vinyl sulfide and trifluoroacetic anhydride followed by oxidation with peroxytrifluoroacetic acid, reacts with electron-rich he