ChemInform Abstract: Preparation of the Pd/C Catalysts: A Molecular-Level Study of Active Site Formation
β Scribed by P. A. Simonov; S. Yu. Troitskii; V. A. Likholobov
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 25 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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Study of Pd-Elimination under Carbonylation Conditions: Regioselective Formation of Esters. -Carbonylation reactions carried out with either the known Ξ· 3 -allylpalladium complexes or with Ξ· 1 -Ξ· 2 -enylpalladium complexes, formed as intermediates at low temperatures, give Ξ²,Ξ³-unsaturated esters su