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ChemInform Abstract: Preparation of Cyclic Sulfites by Transesterification of Diols and Diisopropyl Sulfite.

โœ Scribed by S. A. KING; B. PIPIK; D. A. CONLON; M. BHUPATHY

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
28
Category
Article
ISSN
0931-7597

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Enantiopure Derivatives of 1,1,2-Triphenylethane-1,2-diol by Unusual Ring Opening of Its Cyclic Sulfite. -Reaction of the diastereomeric mixture (II) with the alcohols (III) or the diols (V) leads to the formation of the enantiomerically pure ethers via an SN1-type ring cleavage. Treatment of (II)