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ChemInform Abstract: Preparation of Allylsilanes by the Olefination of Carbonyl Compounds Using β-Silylthioacetals.

✍ Scribed by T. TAKEDA; M. WATANABE; M. A. RAHIM; T. FUJIWARA


Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
29
Category
Article
ISSN
0931-7597

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Trans-Selective Olefination of Carbonyl Compounds by Low-Valent Titanium-Mediated Dehydroxybenzotriazolylation. -A convenient and stereocontrolled olefination of aldehydes and ketones is developed by reacting the carbonyl compounds with lithiated benzotriazole derivatives followed by low-valent tit