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ChemInform Abstract: Preparation of 2-Fluoro-3-aminophenylboronates via Directed ortho-Metalation.

✍ Scribed by Paul E. Zhichkin; Sergiy G. Krasutsky; Catherine M. Beer; W. Martin Rennells; Seung H. Lee; Jin-Ming Xiong


Publisher
John Wiley and Sons
Year
2011
Weight
37 KB
Volume
42
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Regioselective Dire
✍ K. W. STAGLIANO; H. C. MALINAKOVA πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 33 KB πŸ‘ 1 views

Regioselective Directed ortho Metalation of 3H-Naphtho[2,1b]pyrans. Synthesis of Methylteretifolione B. -Treatment of naphthopyrans with tBuLi under controlled conditions results in selective ortho-metalation. Following quenching with electrophiles yields single products. The methyl derivative (II