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ChemInform Abstract: Preparation of 2-C-Hydroxymethyl-D-mannose and -D-glucose and Their Stereospecific and Irreversible Rearrangements to D-gluco- and D-manno- Heptulose under the Conditions of the Bilik Reaction.

✍ Scribed by L. PETRUS; Z. HRICOVINIOVA; M. PETRUSOVA; M. MATULOVA

Publisher: John Wiley and Sons
Year: 2010
Weight: 29 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199725202

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✦ Synopsis

Preparation of 2-C-Hydroxymethyl-D-mannose and -D-glucose and Their Stereospecific and Irreversible Rearrangements to D-glucoand D-manno-Heptulose under the Conditions of the Bilik Reaction.

-A new method for the synthesis of the heptuloses (IV) and (V) by molybdic acid-catalyzed carbon skeleton rearrangement of the 2-C-hydroxymethyl compounds (II) and (III), resp., is presented. -(

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