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ChemInform Abstract: Preparation and Synthetic Applications of Alkene Complexes of Group 9 Transition Metals in [2 + 2 + 2] Cycloaddition Reactions.

✍ Scribed by Nico Weding; Marko Hapke


Publisher
John Wiley and Sons
Year
2011
Weight
18 KB
Volume
42
Category
Article
ISSN
0931-7597

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Abstract

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The preparation and catalytic evaluation of the three group 9 (cyclopentadienyl)metal(trimethylvinylsilane) complexes of the type C 5 H 5 M(H 2 C= CHSiMe 3 ) 2 (M = cobalt, rhodium and iridium) are reported. The complexes were investigated in [2 + 2 + 2] cycloaddition as well as in hydrogenation, hy