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ChemInform Abstract: Preparation and Structural Feature of (η3-Allyl) dicarbonylnitrosyliron Complexes with Planar Chirality.

✍ Scribed by S. NAKANISHI; H. YAMAGUCHI; K. OKAMOTO; T. TAKATA

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Preparation and Structural Feature of (η3-Allyl) dicarbonylnitrosyliron Complexes with Planar Chirality.

-The title compounds (III) and (V) which are versatile reagents for organic transformations are synthesized by complexation of the chiral allyl bromides (I) and (IV). The diastereomers obtained can be separated by chromatography. The structure of the major diastereomer of (IIIa) is supported by X-ray analysis. -(NAKANISHI, S.;

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