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ChemInform Abstract: Preparation and Stille Cross-Coupling Reaction of the First Organotin Reagents of Azulenes. An Efficient Pd(0)-Catalyzed Synthesis of 6-Aryl- and Biazulenes.

โœ Scribed by Tetsuo Okujima; Shunji Ito; Noburo Morita

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
33
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Efficient Synthesis of 1,1-Diaryl 1,2-Dienes via Pd(0)-Catalyzed Coupling of Aryl Halides with Allenic/Propargylic Zinc Reagents.
โœ Shengming Ma; Aibin Zhang ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 30 KB ๐Ÿ‘ 1 views

Efficient Synthesis of 1,1-Diaryl 1,2-Dienes via Pd(0)-Catalyzed Coupling of Aryl Halides with Allenic/Propargylic Zinc Reagents. -The title reaction is proposed to involve oxidative addition of halides to Pd(0) to form an organopalladium intermediate. This is trapped by an allenic or propargylic z