ChemInform Abstract: Preparation and Enantiomer Recognition Behavior of Azophenolic Crown Ethers Containing cis-1-Phenylcyclohexane-1,2-diol as the Chiral Subunit and 2,4-Dinitrophenylazophenol as the Chromophore.
โ Scribed by K. NAEMURA; K. UENO; S. TAKEUCHI; K. HIROSE; Y. TOBE; T. KANEDA; Y. SAKATA
- Book ID
- 112032734
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 28 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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Preparation of Homochiral Azophenolic Crown Ethers Containing 1-Phenylethane-1,2-diol and 2,4,-Dimethyl-3-oxapentane-1,5-diol as a Chiral Subunit: Enantiomer Recognition Behavior Towards Chiral 2-Aminoethanol Derivatives. -The enantiomerically pure crown ethers (VII)-(X) are synthesized. Ether (VII
Enantiomerically pure azophenolic crown ethers 1--4 containing (S)-or (R)l-phenylethane-l,2-diol moieties and (2S,4S)-2,4-dimethyl-3-oxapentane-l,5-diol moiety as a chiral subunit were prepared; crown ethers (S,S,S,S)-I showed high chiral recognition behaviour in complexation with 2-substituted 2-am