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ChemInform Abstract: Preparation and Crystal Structure of the Ternary Carbides Ln12Os5C15 with Ln: Y, Pr, Nd, Sm, Gd—Tm.

✍ Scribed by Thomas Huefken; Klaus H. Wachtmann; Wolfgang Jeitschko


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis


Preparation and Crystal Structure of the Ternary Carbides Ln 12 Os 5 C 15 with Ln: Y, Pr, Nd, Sm, Gd-Tm.

-The title compounds are prepared by arc melting of the elements and subsequent annealing (evacuated silica tube, 1000 • C, 1 month). They crystallize in the hexagonal La 12 Re 5 C 15 type structure, which is refined for Tb 12


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